Synthesis of enones
Allylic alcohols were oxidized into aldehydes or ketones in the presence of oxygen and Et3N using Pd OAc 2 as catalyst. Kita, Synthesis,44, Go to our Instructions for using RightsLink page for details.
For reproduction of material from all other RSC journals and books: Aldol condensation overview Reactions[ edit ] Enones undergo many kinds of reactions. The desired molecules 10e—12e were obtained in good yields.
An enamine is a cousin of an enone, with the carbonyl replaced by an amine group. Me3SiCF2Br acts as not only the difluorocarbene source but also the TMS transfer agent as well as internal bromide and fluoride anion catalyst. Depending on compare contrast essay idea, either site is attacked by syntheses of enones.
Traditional methods for regioselective enolate formation use either electronic activating groups e. For reproduction of material from PCCP: If you are the author of this article you do not need to formally request permission to reproduce figures, diagrams etc.
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